Advances in Biomimetics by Anne George

By Anne George

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Res. , 2009, 44, 288. Copyright 2009 Elsevier. 36 Advances in Biomimetics growth of the crystals, and influenced the crystal morphology. Due to the electrostatic interaction with Ba2+ ions, the negatively charged of polymer polar groups acted as active sites for the nucleation of BaCrO4. Yu et al. (2003) reported that some faces of the BaCrO4 crystal could adsorb negatively charged groups such as –PO3H2, –COOH of polymer by electrostatic attraction and block these faces from further growth. , 2004a,b).

39 Å correspond to the d-spacing of (200) and (011) planes, respectively. This result is in accord with the SAED result. In our experiment, the sample underwent the ripening process. In order to investigate the effect of time on the morphology of BaCrO4, the samples were fabricated for different times. When the time was only 5 min (Fig. 16a), the shuttle-like morphology with relatively uniform sizes was obtained, indicating rapid nucleation and growth process. Sawtooth-like edge and clear growth steps can be seen from the insets of Fig.

4, 283-90. ; Berman, R. ; et al. (2003). DNA-templated carbon nanotube field-effect transistor, Science, 302, 1380. Kim, H. ; Lee, H. ; Knowles, J. C. (2006). Electrospinning biomedical nanocomposite fibers of hydroxyapaite/poly(lactic acid) for bone regeneration. J. Biomed. Mater. Res. Part A, 79A, 643-9. Kim, H. ; Knowles, J. C. & Kim, H. E. (2004). Hydroxyapatite/poly (epsilon-caprolactone) composite coatings on hydroxyapatite porous bone scaffold for drug delivery. Biomaterials, 25, 1279-87.

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