Adsorption on Mesoporous Metal-Organic Frameworks in by Alexander Samokhvalov

By Alexander Samokhvalov

Adsorption and desorption in resolution play major roles in separations, cleansing of waste streams, in purification, chromatography, heterogeneous catalysis, metabolism of medicines, and past. Metal-Organic Frameworks (MOFs) are well-ordered three-dimensional hybrid organic-inorganic polymers which include steel cations and the structure-building natural "linker" devices. Mesoporous MOFs with pore sizes 2-50 nm are really appropriate for adsorption and adsorption-based separations of huge molecules of natural and bio-organic compounds.

Thousands of natural compounds and, particularly, fragrant and heterocyclic compounds are regular as feedstock for commercial chemical synthesis, as positive chemical substances, significant parts of liquid fossil fuels, dyestuffs, business solvents, agricultural chemical compounds, medications, prescribed drugs and private care items (PPCPs), and energetic pharmaceutical components (APIs). there's a powerful curiosity in the direction of synthesis, characterization and experiences of either identified and newly synthesized mesoporous MOFs for adsorption in way to in achieving the excessive adsorption capability, selectivity, and the opportunity of a number of regeneration of "spent" sorbent.

This ebook covers experimental basic learn on utilizing mesoporous MOFs in rising purposes of significant business, environmental and educational significance, specifically purification of water and liquid fossil fuels and in complicated biomedical technologies.

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Extra resources for Adsorption on Mesoporous Metal-Organic Frameworks in Solution for Clean Energy, Environment and Healthcare

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T. Hupp, and O. K. Farha. 2014. Beyond post-synthesis modification: Evolution of metal-organic frameworks via building block replacement. Chemical Society Reviews 43(16):5896–5912. , J. E. Mondloch, E. Tylianakis, P. Ghosh, W. Bury, R. Q. Snurr, J. T. Hupp, and O. K. Farha. 2013. Perfluoroalkane functionalization of NU-1000 via solvent-assisted ligand incorporation: Synthesis and CO2 adsorption studies. Journal of the American Chemical Society 135(45):16801–16804. , C. Mellot-Draznieks, C. Serre, and F.

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Strain-promoted “click” modification of a mesoporous metal–organic framework, J. Am. Chem. , 134(46), 18886–18888. 15 Schematic representation of oriented and functionalized MOF crystals grown on SAM-modified gold substrates (left) followed by the post-synthetic modification of the MOF thin film with dye molecules (right). , 41(14), 3899–3901, 2012. 16 (a) Molecular representations of NU-1000 and (b) schematic representation of solvent-assisted ligand incorporation (SALI). , Perfluoroalkane functionalization of NU-1000 via solvent-assisted ligand incorporation: Synthesis and CO2 adsorption studies, J.

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